Question
Chemistry Question on Thermodynamics terms
One mole of an ideal gas is allowed to expand reversibly and adiabatically from a temperature of 27∘C The work done is 3kJ. The final temperature of the gas is equal to [Cv=20KJ−1]:
A
75 K
B
150 K
C
225 K
D
300 K
Answer
150 K
Explanation
Solution
From first law of thermodynamics, ΔU=q+W As we know that, for adiabatic condition, q=0 ∴ΔU=W…..(1) At constant volume, ΔU=nCvΔT…..(2) From eq n(1)&(2), we have W=nCvΔT…..(3) Given:- Ti=27∘C=(27+273)K=300K Tf=T( say )= ? ΔT=Tf−Ti=(T−300) Cv=20J/K− mol W=−3kJ=−3×103J[∵ Work done by the gas is negative ] T−3000=1×20×(T−300) ⇒T=300−150=150K