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Question

Chemistry Question on Spontaneity

One mole of a perfect gas expands isothermally to tentimes its original volume. The change in entropy is

A

0.1 R

B

2.303 R

C

10.0 R

D

100.0 R

Answer

2.303 R

Explanation

Solution

qrev=Wrev=2.303q_{rev} = - W_{rev} = 2.303 nRT log V2V1\frac{V_2}{V_1} ΔS=qrevT\Delta S = \frac{q_{rev}}{T} = 2.303 nR log V2V1\frac{V_2}{V_1} Here n = 1, V2V1=10\frac{V_2}{V_1} = 10 \therefore ΔS=2.303×1×R×log10\Delta S = 2.303 \times 1 \times R \times log \, 10 = 2.303×R×1=2.3032.303 \times R \times 1 = 2.303 R