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Question: One mole of a mono-atomic gas behaving as per PV = nRT at 27°C is subjected to reversible isoentropi...

One mole of a mono-atomic gas behaving as per PV = nRT at 27°C is subjected to reversible isoentropic compression untill final temperature reaches 327°C. If the initial pressure was 1.0 atm then the value of lnP (final) is –

(givenln 2 = 0.7)

A

1.75

B

0.176

C

1.0395

D

2.0

Answer

1.75

Explanation

Solution

Isoentropic process is adiabatic process. So

(T1T2)γ=(P1P2)γ1(300600)5/3=(PiPf)2/3\left( \frac{T_{1}}{T_{2}} \right)^{\gamma} = \left( \frac{P_{1}}{P_{2}} \right)^{\gamma –1} \Rightarrow \left( \frac{300}{600} \right)^{5/3} = \left( \frac{P_{i}}{P_{f}} \right)^{2/3}

̃ (12)5/3=(1Pf)2/3\left( \frac{1}{2} \right)^{5/3} = \left( \frac{1}{P_{f}} \right)^{2/3}

̃ 53\frac{5}{3} ln 2 = 23\frac{2}{3}ln Pf ̃ lnPf = 52\frac{5}{2}ln 2 = 1.75