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Question

Physics Question on Kinetic molecular theory of gases

One litre of oxygen at a pressure of 1atm1 \,atm and two litres of nitrogen at a pressure of 0.5atm0.5\, atm, are introduced into a vessel of volume 1L1\, L. If there is no change in temperature, the final pressure of the mixture of gas (in atm) is

A

1.5

B

2.5

C

2

D

4

Answer

2

Explanation

Solution

Ideal gas equation is given by
pV=nRT...(i)pV = nRT ...(i)
For oxygen, p=1atm,V=1L,n=n0p=1 atm , V =1 L , n = n _{0}
Therefore equation (i) becomes
1×1=n0,RT\therefore 1 \times 1= n _{0,} RT
n02=1RT\Rightarrow n _{0_{2}}=\frac{1}{ RT }
For nitrogen p=0.5atm,V=2L,n=nNp=0.5 atm , V =2 L , n = nN
0.5×2=nN2RT\therefore 0.5 \times 2= n _{ N _{2}} RT
nN2=1RT\Rightarrow n _{ N _{2}}=\frac{1}{ RT }
For mixture of gas
pmixVmix=nmixRTp _{mix} V _{mix}= n _{mix} RT
Here, nmix=nO+nN2n _{mix}= n O + n _{ N _{2}}
pmixVmixRT=1RT+1RT\therefore \frac{ p _{mix} V _{mix}}{ RT }=\frac{1}{ RT }+\frac{1}{ RT }
pmixVmix=2\Rightarrow p _{mix} V _{mix}=2