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Question

Chemistry Question on Buffer Solutions

One litre of 0.15MNa2SO30.15\, M\, Na _{2} SO _{3} aqueous solution is mixed with 500mL500\, mL of 0.2MK2Cr2O70.2\, M\, K _{2} Cr _{2} O _{7} aqueous solution in acid medium. What is the number of moles of K2Cr2O7K _{2} Cr _{2} O _{7} remaining in the solution after the reaction?

A

0.1

B

0.0125

C

0.025

D

0.05

Answer

0.05

Explanation

Solution

When 0.15MNa2CO30.15\, M\, Na _{2} CO _{3} (1 L) mixed with 0.2M0.2\, M K2Cr2O7(5L)K _{2} Cr _{2} O _{7}(5\, L ) than total molarity (M).(M) . M=M1V1+M2V2V3M =\frac{M_{1} V_{1}+M_{2} V_{2}}{V_{3}} M=0.15×1+0.2×0.51.5M =\frac{0.15 \times 1+0.2 \times 0.5}{1 .5} M=0.15mol/LM =0.15\, mol / L Remaining mole of K2Cr2O7=0.20.15K _{2} Cr _{2} O _{7}=0.2-0.15 =0.05mol/L=0.05\, mol / L