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Question

Chemistry Question on Some basic concepts of chemistry

One gram mole of a gas at NTP occupies 22.4L22.4\, L. This fact was derived from

A

law of gaseous volumes

B

Avogadro's hypothesis

C

Berzelius hypothesis

D

Dalton's atomic theory

Answer

Avogadro's hypothesis

Explanation

Solution

According to ideal gas equation, PV=nRTP V=n R T Putting the standard conditions, i.e. P=1P =1 atm n=1n=1 mole, R=0.0821LR=0.0821\, L atm K1K^{-1}, mol 1,^{-1}, T=273KT=273\, K V=nRTP=1 mole ×0.0821LatmK1mol1×273K1atmV=\frac{n R T}{P}=\frac{1 \text { mole } \times 0.0821 L\,atm K^{-1} mol ^{-1} \times 273\, K }{1 atm } V=22.4V=22.4