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Question

Question: On the electrolysis of aqueous solution of sodium sulphate, on cathode we get....

On the electrolysis of aqueous solution of sodium sulphate, on cathode we get.

A

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A

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B

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C

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Answer

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Explanation

Solution

Water is reduced at the cathode and oxidized at the anode instead of Na+Na^{+}and SO42SO_{4}^{2 -}.

Cathode : 2H2O+2eH2+2OH2H_{2}O + 2e^{-} \rightarrow H_{2} + 2OH^{-}

Anode : H2O2H++12O2+2eH_{2}O \rightarrow 2H^{+} + \frac{1}{2}O_{2} + 2e^{-}.