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Question: Obtain a relation between half-life of a radioactive substance and decay constant (\[\lambda \])...

Obtain a relation between half-life of a radioactive substance and decay constant (λ\lambda )

Explanation

Solution

Take population as N0{{\text{N}}_0} in t=0 and N at any given time t.

Complete step by step solution:
Given, we need to find out the relation between half life of a radioactive substance and decay constant.
Now, let N be the size of the population of radioactive atoms at a given time t. dN is the amount by which the population of the radioactive atoms decreases in time dT
So, the rate of change can be given by the equation:

dNdT=λN dNN=λdT  \Rightarrow \dfrac{{{\text{dN}}}}{{{\text{dT}}}} = - \lambda {\text{N}} \\\ \Rightarrow \dfrac{{{\text{dN}}}}{{\text{N}}} = - \lambda {\text{dT}} \\\

Integrating both sides we get,

dNN=λdT N = N0eλT  \Rightarrow \int {\dfrac{{{\text{dN}}}}{{\text{N}}}} = - \lambda \int {{\text{dT}}} \\\ \Rightarrow {\text{N = }}{{\text{N}}_0}{e^{ - \lambda {\text{T}}}} \\\

Where N0{{\text{N}}_0} is the population of initial radioactive atoms at time T = 0.

Half life is the time required to decay half the original population of radioactive atoms.
N = N02 at T = T(12){\text{N = }}\dfrac{{{{\text{N}}_0}}}{2}{\text{ at T = }}{{\text{T}}_{(\dfrac{1}{2})}}
N02=N0eλT(12)\Rightarrow \dfrac{{{{\text{N}}_0}}}{2} = {{\text{N}}_0}{e^{ - \lambda {{\text{T}}_{(\dfrac{1}{2})}}}}
On cancelling out N0{{\text{N}}_0}we get,
12=eλT(12)\Rightarrow \dfrac{1}{2} = {e^{ - \lambda {{\text{T}}_{(\dfrac{1}{2})}}}}

Now on cross-multiplying we get,
eλT(12)=2\Rightarrow {e^{\lambda {{\text{T}}_{(\dfrac{1}{2})}}}} = 2
Putting the logarithm function on both sides we get,
logeeλT(12)=loge2{\log _e}{e^{\lambda {{\text{T}}_{(\dfrac{1}{2})}}}} = {\log _e}2
Using formula and cancelling out log in LHS we get,
λT(12)=loge2\Rightarrow \lambda {{\text{T}}_{(\dfrac{1}{2})}} = {\log _e}2
Making T as the subject of the formula we get,
T(12)=loge2λ\Rightarrow {{\text{T}}_{(\dfrac{1}{2})}} = \dfrac{{{{\log }_e}2}}{\lambda }
On putting the value of log2 we get,
T(12)=0.693λ\Rightarrow {{\text{T}}_{(\dfrac{1}{2})}} = \dfrac{{0.693}}{\lambda }
Thus, the decay constant and half life of a radioactive substance is related by
T(12)=0.693λ{{\text{T}}_{(\dfrac{1}{2})}} = \dfrac{{0.693}}{\lambda }

Additional information:
Half-life of a radioactive substance can be defined as the time taken for a given amount of the substance to become reduced by half as a consequence of decay, and therefore, the emission of radiation .

Note: Decay constant is proportionality constant between the size of a population of radioactive atoms and the rate at which the population decreases because of radioactive decay.