Solveeit Logo

Question

Question: Numerical based on relationship between density,molar mass,and,and edge length of unit cell on chemi...

Numerical based on relationship between density,molar mass,and,and edge length of unit cell on chemistry

Answer

To solve a numerical problem based on the relationship between density, molar mass, and edge length of a unit cell, we use the following formula:

ρ=Z×Ma3×Na\rho = \frac{Z \times M}{a^3 \times N_a}

Where:

  • ρ\rho is the density of the crystalline substance.
  • ZZ is the number of atoms (or molecules) per unit cell. This depends on the type of unit cell (e.g., Z=1 for simple cubic, Z=2 for body-centered cubic (BCC), Z=4 for face-centered cubic (FCC)).
  • MM is the molar mass of the substance.
  • aa is the edge length of the unit cell (assuming a cubic unit cell).
  • NaN_a is Avogadro's number (6.022×1023 mol16.022 \times 10^{23} \text{ mol}^{-1}).

This formula can be rearranged to solve for any of the variables if the others are known. For example, to find the edge length aa:

a3=Z×Mρ×Naa^3 = \frac{Z \times M}{\rho \times N_a} a=(Z×Mρ×Na)1/3a = \left(\frac{Z \times M}{\rho \times N_a}\right)^{1/3}

Explanation

Solution

To solve a numerical problem based on the relationship between density, molar mass, and edge length of a unit cell, we use the following formula:

ρ=Z×Ma3×Na\rho = \frac{Z \times M}{a^3 \times N_a}

Where:

  • ρ\rho is the density of the crystalline substance.
  • ZZ is the number of atoms (or molecules) per unit cell. This depends on the type of unit cell (e.g., Z=1 for simple cubic, Z=2 for body-centered cubic (BCC), Z=4 for face-centered cubic (FCC)).
  • MM is the molar mass of the substance.
  • aa is the edge length of the unit cell (assuming a cubic unit cell).
  • NaN_a is Avogadro's number (6.022×1023 mol16.022 \times 10^{23} \text{ mol}^{-1}).

This formula can be rearranged to solve for any of the variables if the others are known. For example, to find the edge length aa:

a3=Z×Mρ×Naa^3 = \frac{Z \times M}{\rho \times N_a} $a = \left(\frac{Z \times M}{\rho \times N_a}\right)^{1/3}