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Question

Chemistry Question on Atomic Structure

Number of spectral lines obtained in He+ spectra, when an electron makes transition from fifth excited state to first excited state will be __________.

Answer

To calculate the number of spectral lines obtained during the transition of an electron from the fifth excited state to the first excited state in the He+ ion, we use the formula for the maximum number of spectral lines during a transition:

Number of spectral lines = n2(n2+1)2n1(n1+1)2\frac{n_2(n_2 + 1)}{2} - \frac{n_1(n_1 + 1)}{2}

Where:
n1n_1 is the final state (ground state or first excited state).
n2n_2 is the initial state (fifth excited state).

Assign Values:

  • For the first excited state: n1=2n_1 = 2
  • For the fifth excited state: n2=6n_2 = 6

Calculate the Maximum Number of Lines:

Δn=n2n1=62=4\Delta n = n_2 - n_1 = 6 - 2 = 4

The maximum number of spectral lines is given by:

Number of lines=n2(n2+1)2n1(n1+1)2\text{Number of lines} = \frac{n_2(n_2 + 1)}{2} - \frac{n_1(n_1 + 1)}{2} =6(6+1)22(2+1)2= \frac{6(6 + 1)}{2} - \frac{2(2 + 1)}{2} =6×722×32= \frac{6 \times 7}{2} - \frac{2 \times 3}{2} =213=18= 21 - 3 = 18

Since we are considering all possible transitions from n2=6n_2 = 6 to n1=2n_1 = 2, we have:

Final Calculation:

Maximum number of spectral lines=Δn(Δn+1)2=4(4+1)2=202=10\text{Maximum number of spectral lines} = \frac{\Delta n (\Delta n + 1)}{2} = \frac{4(4 + 1)}{2} = \frac{20}{2} = 10

Thus, the number of spectral lines obtained in He+ spectra when an electron transitions from the fifth excited state to the first excited state is: 10