Solveeit Logo

Question

Question: Number of \[dibromo\] derivatives produced when \[bromine\] is added to \[\left( {3S} \right) - 3 - ...

Number of dibromodibromo derivatives produced when brominebromine is added to (3S)3Methyl Cyclohexene\left( {3S} \right) - 3 - Methyl{\text{ }}Cyclohexene in 1,2dichloroethane1,2 - dichloroethane are:
A.22
B.33
C.44
D.66

Explanation

Solution

dibromodibromo derivatives as the name suggests contains two brominebromine groups in the molecule. These reactions are carried out depending upon the amount of brominebromine and thus bromination takes place with or without the help of catalysts.

Complete answer:
(3S)3Methyl Cyclohexene\left( {3S} \right) - 3 - Methyl{\text{ }}Cyclohexene is an organic compound consisting MethylMethyl as a functional group, an unsaturated carbon bond and a ring. The number on the structure represents the placement of these functional groups in the compound. The alphabet SS represents the type of configuration. For that we must know the enantiomers. Enantiomers are non-imposable mirror images. The absolute configuration refers to the spatial arrangement of the atoms of a chiral molecular entity. The SS and RR configuration indicates the relative spatial orientation of each atom in a molecule with a non-superimposable mirror image. Here SS means the spatial isomer that has its relative direction of priority order in an anticlockwise direction whereas RR means in clockwise direction.
For that one must be familiar with the bromination process. As one can predict from the name that it involves the brominebromine element. Therefore bromination is the process or reaction in which brominebromine is introduced into a molecule and no other elements are introduced into a molecule. In a benzenebenzene ring bromination takes place by electrophilic aromatic substitution.
Now let's find out the reaction of (3S)3Methyl Cyclohexene\left( {3S} \right) - 3 - Methyl{\text{ }}Cyclohexene in 1,2dichloroethane1,2 - dichloroethane to find out the number of dibromodibromo derivatives it produced.
When brominebromine is added to (3S)3Methyl Cyclohexene\left( {3S} \right) - 3 - Methyl{\text{ }}Cyclohexene in 1,2dichloroethane1,2 - dichloroethane the number of dibromodibromo derivatives formed are 2.
They are (1S,2S,3S)1,2dibromo3methylcyclohexane\left( {1S,2S,3S} \right) - 1,2 - dibromo - 3 - methylcyclohexane and (1R,2R,3S)1,2dibromo3methylcyclohexane\left( {1R,2R,3S} \right) - 1,2 - dibromo - 3 - methylcyclohexane
The reaction and their structure are as follow-

Note:
The products formed from the above reaction are similar, it is only the spatial orientation that differs. Also the knowledge of halogenation and electrophilic aromatic reaction will help you predict the product of the reaction of the reactants provided for such type of question.