Solveeit Logo

Question

Chemistry Question on Chemical bonding and molecular structure

NO+NO^{+} has bond order

A

2

B

2.5

C

3

D

3.5

Answer

3

Explanation

Solution

Bond order of NO+NO ^{+} can be calculated by following formula.

Bond order =NbNa2=\frac{N_{b}-N_{a}}{2}

The increasing order of energies of various molecular orbitals for NO+NO ^{+} is given below

NO+(14)=σls2,σ1s2,σ2s2,σ2s2,(π2px+π2py)NO ^{+}(14)=\sigma l s^{2}, \sigma^{*} 1 s^{2}, \sigma 2 s^{2}, \sigma^{*} 2 s^{2},\left(\pi 2 p_{x}+\pi 2 p_{y}\right)
σ2pz2(π2px0=π2py0),σ2pz0\sigma 2 p_{z^{\prime}}^{2}\left(\pi^{*} 2 p_{x}^{0}=\pi^{*} 2 p_{y}^{0}\right), \sigma^{*} 2 p_{z}^{0}

The bond order can be calculated as

Bond order =NbNa2=\frac{N_{b}-N_{a}}{2}
=1042=62=3=\frac{10-4}{2}=\frac{6}{2}=3