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Question

Question: Nitration and chlorination of benzene are...

Nitration and chlorination of benzene are

A

Nitration and chlorination of benzene are

B

Electrophilic and nucleophilic substitution respectively.

C

Electrophilic substitution in both are the reactions.

D

Nucleophilic substitution in both the reactions.

Answer

Electrophilic substitution in both are the reactions.

Explanation

Solution

: Nitration is carried out by the help of

electrophile NO2+\mathrm { NO } _ { 2 } ^ { + }

HNO3+2H2SO4NO2++2HSO4+H3O+\mathrm { HNO } _ { 3 } + 2 \mathrm { H } _ { 2 } \mathrm { SO } _ { 4 } \rightarrow \mathrm { NO } _ { 2 } ^ { + } + 2 \mathrm { HSO } _ { 4 } ^ { - } + \mathrm { H } _ { 3 } \mathrm { O } ^ { + }

Halogenation is carried out by the help of

electrophile Cl+(X+)\mathrm { Cl } ^ { + } \left( \mathrm { X } ^ { + } \right)

Cl2+FeCl3Cl++FeCl4\mathrm { Cl } _ { 2 } + \mathrm { FeCl } _ { 3 } \rightarrow \mathrm { Cl } ^ { + } + \mathrm { FeCl } _ { 4 } ^ { - }