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Question

Chemistry Question on Nomenclature of Coordination Compounds

Nessler's reagent is

A

KHgI4KHgI_{4}

B

K2HgI4+NH4OHK_{2}HgI_{4}+NH_{4}OH

C

[Ne]3s23p3[Ne]3s^{2}3p^{3}

D

KHgI4+NH4OHKHgI_{4}+NH_{4}OH

Answer

[Ne]3s23p3[Ne]3s^{2}3p^{3}

Explanation

Solution

Nessler's reagent =K2HgI4+KOH= K _{2} HgI _{4}+ KOH 2K2HgI4+NH4Cl+4KOHNH2HgOHgIiodide of Million’s base (brown ppt) 2 K _{2} HgI _{4}+ NH _{4} Cl +4 KOH \rightarrow \underset{\text{iodide of Million's base (brown ppt) }}{NH _{2} HgOHgI} +7KI+KCl+3H2O+7 KI + KCl +3 H _{2} O Nessler's reagent is required for detection of ammonia. It gives brown ppt with ammonium salt.