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Question: Neon has two isotopes, \(^{20}{\text{Ne}}\) and \(^{22}{\text{Ne}}\). If atomic weight of neon is \(...

Neon has two isotopes, 20Ne^{20}{\text{Ne}} and 22Ne^{22}{\text{Ne}}. If atomic weight of neon is 20.220.2, then the ratio of the relative abundance of the isotopes is:
A. 1:91:9
B. 9:19:1
C. 1:71:7
D. 7:17:1

Explanation

Solution

The average atomic mass is determined by adding the product of the mass of each isotope and its relative abundance. We will assume that the relative abundance of one isotope is X, and the relative abundance of the second isotope will be100X100 - {\text{X}}. By putting the values of each in the average atomic mass formula we can determine the value of X that is the relative abundance.

Complete solution:
The average atomic mass is the sum of the product of the mass of isotope and its relative abundance.
The formula of the average atomic mass is as follows:
Averageatomicmass = isotopemass \timesrelative abundance of that isotope{\text{Average}}\,{\text{atomic}}\,{\text{mass}}\,{\text{ = }}\,\sum {{\text{isotope}}\,{\text{mass}}\,{\text{ \times }}\,{\text{relative abundance}}} {\text{ of that isotope}}
For the two isotopes of neon the formula can be written as follows:
Averageatomicmass = (massof20Ne×abundanceof 20Ne)+(massof22Ne×abundanceof 22Ne){\text{Average}}\,{\text{atomic}}\,{\text{mass}}\,{\text{ = }}\,\,\left( {{\text{mass}}\,{\text{of}}{\,^{20}}{\text{Ne}}\,\, \times \,\,{\text{abundance}}\,{\text{of}}{{\text{ }}^{20}}{\text{Ne}}\,} \right) + \left( {{\text{mass}}\,{\text{of}}{\,^{22}}{\text{Ne}}\,\, \times \,\,{\text{abundance}}\,{\text{of}}{{\text{ }}^{22}}{\text{Ne}}\,} \right)\,
We assume that the relative abundance of 20Ne^{20}{\text{Ne}} in the sample is X% and the relative abundance of 22Ne^{22}{\text{Ne}} in the sample is 100X100 - {\text{X}}%.
Mass of 20Ne^{20}{\text{Ne}} isotope is 2020and the mass of 22Ne^{22}{\text{Ne}} is 2020.
To determine the value of X, on substituting 20.220.2for average atomic mass, 2020for mass of20Ne^{20}{\text{Ne}}, 2222for mass of22Ne^{22}{\text{Ne}}, X for relative abundance of 20Ne^{20}{\text{Ne}} and 100X100 - {\text{X}}% for relative abundance of22Ne^{22}{\text{Ne}}.
20.2 = (20×X100)+(22×100X100)20.2\,{\text{ = }}\,\,\left( {20\,\, \times \,\,\dfrac{{\text{X}}}{{{\text{100}}}}\,} \right) + \left( {22\,\, \times \,\,\dfrac{{100 - {\text{X}}}}{{{\text{100}}}}\,} \right)\,
20.2 = 20X100+220010022X10020.2\,{\text{ = }}\,\,\dfrac{{20\,{\text{X}}}}{{{\text{100}}}} + \dfrac{{2200}}{{{\text{100}}}} - \dfrac{{{\text{22X}}}}{{{\text{100}}}}\,\,
2020 = 20X + 220022X2020\,{\text{ = }}\,\,20{\text{X}}\,{\text{ + }}\,22{\text{00}}\, - 22\,{\text{X}}\,\,
2X = 180{\text{2X = }}\,180
X = 90{\text{X = }}\,90
So, the relative abundance of 20Ne^{20}{\text{Ne}} in the sample is 9090%.
We will determine the relative abundance of 22Ne^{22}{\text{Ne}} as follows:
On substituting 9090% for relative abundance of 22Ne^{22}{\text{Ne}} in 100X100 - {\text{X}}%.
10090=10100 - 90\, = 10
So, the relative abundance of 22Ne^{22}{\text{Ne}} in the sample is 1010%.
So, the relative abundance of the isotopes is,
20Ne^{20}{\text{Ne}} : 22Ne^{22}{\text{Ne}}
90:1090:10
9:19:1
Therefore, option (B) 9:19:1 is correct.

Note: The chemical elements that have the same atomic number but different number of neutrons are known as isotopes. The isotopes have the same number of protons and hence represent the same element. The relative abundance of the isotopes is the percent amount of isotopes which is occurring naturally. The total relative abundance of all the isotopes of an element is considered as 100100%.