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Question

Chemistry Question on d block elements

Native silver metal forms a water soluble complex with a dilute aqueous solution of NaCNNaCN in the presence of

A

nitrogen

B

oxygen

C

carbon dioxide

D

argon

Answer

oxygen

Explanation

Solution

A water soluble complex with silver and dilute aqueous solution of NaCN is Na[Ag(CN)2)Na[Ag(CN)_2) In the cyanide process, the native silver is crushed and treated with aqueous NaCN solution and aerated.
4Ag+8NaCN+2H2O+O24Na[Ag(CN)2]+4NaOH4Ag+8NaCN+2H_2O+O_2\rightarrow 4Na[Ag(CN)_2]+4NaOH