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Question

Question: NaOH is prepared by the method....

NaOH is prepared by the method.

A

Down’s cell

B

Castner cell

C

Solvay process

D

Castner Kellner cell

Answer

Castner Kellner cell

Explanation

Solution

The cell involves the following reaction,

NaClNaClNa++ClNa^{+} + Cl^{-}

At anode : 2Cl2Cl+2eCl22Cl^{-} \rightarrow 2Cl + 2e \rightarrow Cl_{2}

At cathode : Na++eNaNa^{+} + e \rightarrow Na

Na+HgNa + Hg \rightarrowamalgam

At anode : NaNa -amalgamNa++Hg+e\rightarrow Na^{+} + Hg + e

At cathode : 2H2O+2eH2+2OH2H_{2}O + 2e \rightarrow H_{2} \uparrow + 2OH^{-}