Question
Question: Name the species which is isoelectronic with \({ N }^{ 3- }\)....
Name the species which is isoelectronic with N3−.
Solution
Hint: To answer this question you should know the meaning of isoelectronic. Those species which have a similar number of electrons are called isoelectronic. Now, you can easily answer this question.
Complete step by step answer:
The atomic number of N is 7, so it has 7 electrons. In N3− there is a charge of more 3 electrons, that makes the total electron count equal to 10 (7+3)
To find other isoelectronic species we need species that have 10 electrons. Some examples are -
O2−, F−, Na+, Mg2+, Al3+
The atomic number of oxygen is 8 and O2− has 10 electrons.
The atomic number of fluorine is 9 and F− has 10 electrons.
The atomic number of sodium is 11 and Na+ has 10 electrons.
The atomic number of magnesium is 12 and Mg2+ has 10 electrons.
The atomic number of aluminum is 13 and Al3+ has 10 electrons.
We can see that all the given species have the same number of electrons (10 electrons ) so, all are isoelectronic species.
Therefore, we gave examples of isoelectronic species with N3−.
Note: We know, the ionic radii of isoelectronic species decrease with an increase in atomic number because the magnitude of nuclear charge increases with increasing atomic number.
increasing order of radii,
Al3+(Z = 13) < Mg2+( Z = 12 ) < Na+ ( Z = 11) < F− (Z = 9) < O2−(Z = 8) < N3− (Z = 7)