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Chemistry Question on Haloalkanes And Haloarenes

Name the following halides according to the IUPAC system and classify them as alkyl, allyl, benzyl (primary, secondary, tertiary), vinyl or aryl halides:
(i) (CH3)2CHCH(Cl)CH3(CH_3)_2CHCH(Cl)CH_3
(ii) CH3CH2CH(CH3)CH(C2H5)Cl\text{CH}_3\text{CH}_2\text{CH}(\text{CH}_3)\text{CH}(\text{C}_2\text{H}_5)\text{Cl}
(iii) CH3CH2C(CH3)2CH2I\text{CH}_3\text{CH}_2\text{C}(\text{CH}_3)_2\text{CH}_2\text{I}
(iv) (CH3)3CCH2CH(Br)C6H5(CH_3)_3CCH_2CH(Br)C_6H_5
(v) CH3CH(CH3)CH(Br)CH3\text{CH}_3\text{CH}(\text{CH}_3)\text{CH(Br)CH}_3
(vi) CH3C(C2H5)2CH2Br\text{CH}_3\text{C(C}_2\text{H}_5)_2\text{CH}_2\text{Br}
(vii) CH3C(Cl)(C2H5)CH2CH3\text{CH}_3\text{C(Cl)(C}_2\text{H}_5)\text{CH}_2\text{CH}_3
(viii) CH3CH=C(Cl)CH2CH(CH3)2\text{CH}_3\text{CH}=C(Cl)\text{CH}_2\text{CH}(\text{CH}_3)_2
(ix) CH3CH=CHC(Br)(CH3)2\text{CH}_3\text{CH}=CHC(Br)(\text{CH}_3)_2
(x) p-ClC6H4CH2CH(CH3)2\text{p-ClC}_6\text{H}_4\text{CH}_2\text{CH}(\text{CH}_3)_2
(xi) m-ClCH2C6H4CH2C(CH3)3\text{m-ClCH}_2\text{C}_6\text{H}_4\text{CH}_2\text{C(CH}_3)_3
(xii) o-Br-C6H4CH(CH3)CH2CH3\text{o-Br-C}_6\text{H}_4\text{CH(CH}_3\text{)CH}_2\text{CH}_3

Answer

(i) 2−Chloro−3−methylbutaneSecondary alkyl halide

2−Chloro−3−methylbutane (Secondary alkyl halide)

(ii) 3−Chloro−4−methyhexane Secondary alkyl halide

3−Chloro−4−methyhexane (Secondary alkyl halide)

(iii) 1−Iodo−2,2−dimethylbutanePrimary alkyl halide

1−Iodo−2,2−dimethylbutane (Primary alkyl halide)

(iv)1−Bromo−3,3−dimethyl−1−phenylbutaneSecondary benzyl halide

1−Bromo−3,3−dimethyl−1−phenylbutane (Secondary benzyl halide)

(v) 2−Bromo−3−methylbutane Secondary alkyl halide

2−Bromo−3−methylbutane (Secondary alkyl halide)

(vi) 1−Bromo−2−ethyl−2−methylbutane Primary alkyl halide

1−Bromo−2−ethyl−2−methylbutane (Primary alkyl halide)

(vii) 3−Chloro−3−methylpentaneTertiary alkyl halide

3−Chloro−3−methylpentane (Tertiary alkyl halide)

(viii) 3−Chloro−5−methylhex−2−eneVinyl halide

3−Chloro−5−methylhex−2−ene (Vinyl halide)

(ix) 4−Bromo−4−methylpent−2−eneAllyl halide

4−Bromo−4−methylpent−2−ene (Allyl halide)

(x) 1−Chloro−4−2−methylpropyl benzeneAryl halide

1−Chloro−4−(2−methylpropyl) benzene (Aryl halide)

(xi) 1−Chloromethyl−3−2,2−dimethylpropyl benzenePrimary benzyl halide

1−Chloromethyl−3−(2,2−dimethylpropyl) benzene (Primary benzyl halide)

(xii) 1−Bromo−2−1−methylpropyl benzene Aryl halide

1−Bromo−2−(1−methylpropyl) benzene (Aryl halide)