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Question

Chemistry Question on Chemical bonding and molecular structure

NaCl(aq)NaCl_(aq) gives a white precipitate with AgNO3AgNO_{3} solution but CCl4CCl_{4} or CHCl3CHCl_{3} does not, because

A

NaClNaCl is a covalent compound and forms AgClAgCl as white ppt

B

NaClNaCl is an ionic compound and forms AgClAgCl as white ppt

C

CCl4CCl_{4} and CHCl3CHCl_{3} are ionic compound

D

none of these

Answer

NaClNaCl is an ionic compound and forms AgClAgCl as white ppt

Explanation

Solution

NaClNaCl being an ionic compound and thus reacts with AgNO3(aq)AgNO_{3}{(aq)} to give ionic reaction, forming AgClAgCl as white ppt. CCl4CCl_{4} and CHCl3CHCl_{3} being covalent do not furnish ClCl^{-} ions in solution. NaCl+AgNO3AgCl+NaNO3NaCl + AgNO_3\rightarrow AgCl + NaNO_3