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Question

Chemistry Question on Equilibrium Constant

N2+3H22NH3N _{2}+3 H _{2} \rightleftharpoons 2 NH _{3} The equilibrium constant for the reaction is KK, then the equilibrium constant or the equilibrium for the reaction given beloow is: NH312N2+32H2NH _{3} \rightleftharpoons \frac{1}{2} N _{2}+\frac{3}{2} H _{2}

A

1/K1/K

B

1/K21/K^2

C

K\sqrt{K}

D

1K\frac {1} {\sqrt{K}}

Answer

1K\frac {1} {\sqrt{K}}

Explanation

Solution

N2+3H22NH3N _{2}+3 H _{2} \rightleftharpoons 2 NH _{3} [NH3]2[N2][H2]3=k1=k\frac{\left[ NH _{3}\right]^{2}}{\left[ N _{2}\right]\left[ H _{2}\right]^{3}}=k_{1}=k NH312N2+32H2NH _{3} \rightleftharpoons \frac{1}{2} N _{2}+\frac{3}{2} H _{2} K2=[N2]1/2[H2]3/2[NH3]K _{2} =\frac{\left[ N _{2}\right]^{1 / 2}\left[ H _{2}\right]^{3 / 2}}{\left[ NH _{3}\right]} On squaring both sides, k22=[N2][H2]3[NH3]2k_{2}^{2}=\frac{\left[ N _{2}\right]\left[ H _{2}\right]^{3}}{\left[ NH _{3}\right]^{2}} k22=1k1k_{2}^{2}=\frac{1}{ k _{1}} 1k1=1k\frac{1}{\sqrt{k_{1}}}=\frac{1}{\sqrt{k}}