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Question: Molarity of liquid \[HCl\] will be, if density of solution is \[1.17gm/cc\]?...

Molarity of liquid HClHCl will be, if density of solution is 1.17gm/cc1.17gm/cc?

Explanation

Solution

Molarity represents the strength of a substance in solution. It is the ratio of the moles of solute dissolved in a litre of solution.

Complete step by step answer: HClHCl is hydrochloric acid whose density is 1.17gm/cc1.17gm/cc. We know that 1cc1cc is equal to 1mL1mLas cccc and mLmL are different names of the same volume. The unit cccc stands for cubic centimeters and mLmL stands for milliliters.
1mL1mL of HClHCl contains 1.17gm1.17gm. Therefore 1L1L or 1000mL1000mL of HClHCl contains 1.17×10001.17 \times 1000= 1170gm1170gm.
In order to determine the moles of HClHCl present in 1170gm1170gm we need to determine the molar or molecular mass of HClHCl.
Molar mass of HClHCl = atomic mass of HH + atomic mass of ClCl.
\Rightarrow 1+35.51 + 35.5 = 36.5gm36.5gm.
Thus the moles of HClHCl in 1170gm1170gm = weight of HClmolar mass of HCl\dfrac{{weight{\text{ }}of{\text{ }}HCl}}{{molar{\text{ }}mass{\text{ }}of{\text{ }}HCl}}
\Rightarrow 117036.5\dfrac{{1170}}{{36.5}} = 32.05moles32.05moles.
As, morality is determined as the ratio of number of moles and volume of solution in litre, so the molarity of HClHCl liquid will be
Molarity = no. of molesvolume in litre\dfrac{{no.{\text{ }}of{\text{ }}moles}}{{volume{\text{ }}in{\text{ }}litre}}
\Rightarrow 32.051\dfrac{{32.05}}{1} = 32.05M32.05M.

Note: Molarity is also referred to as molar concentration of a solution. Similar term molality should not be confused with morality. Molarity is expressed in upper case as MM and molality is expressed in lower case as mm. The basic difference between the two lies in mass vs. volume. Molality is the ratio of moles of solute dissolved in kilograms of solvent. So the unit is mol/kgmol/kg or mm. Both are the measure of a substance concentration in solution. Density is the measure of compactness of a substance in solid, liquid or gas phase. It is the ratio of mass and volume of the substance. So more the density of a substance less will be the volume and vice versa. The density of water is 1gm/mL1gm/mL.