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Question

Chemistry Question on Spontaneity

Molar enthalpy change for melting of ice is 6kJ/mol6\, kJ / mol. Then the internal energy change (in kJ/molk J / mol ) when 11 mole of water is converted into ice at 11 atm at 0C0^{\circ} C is Empty QImg

A

RT/1000

B

6

C

6-(RT/1000)

D

6+(RT/1000)

Answer

6

Explanation

Solution

Given, ΔH=6kJ/mol\Delta H=6\, kJ / mol ΔU=?\Delta U=? H2O(l)Ice(s)H_{2} O(l) Ice(s) ΔH=ΔU+ΔngRT\because \Delta H=\Delta U+\Delta n_{g} R T Here, Δng=0\Delta n_{g}=0 ΔH=ΔU\therefore \Delta H=\Delta U ΔU=6kJ/mol\Rightarrow \Delta U=6\, kJ / mol