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Question

Chemistry Question on Solutions

Molality of an aqueous solution of urea is 4.44 m. Mole fraction of urea in solution is x × 10–3. Value of x is _______. (integer answer)

Answer

Molality (mm) of urea is given as 4.44 mm, meaning 4.44 moles of urea are dissolved in 1000 g of water.
Step 1: Mole fraction formula
Xurea=Moles of ureaMoles of urea+Moles of waterX_{\text{urea}} = \frac{\text{Moles of urea}}{\text{Moles of urea} + \text{Moles of water}}
Step 2: Calculate moles of water
Mass of water=1000g,Molar mass of water=18g/mol.\text{Mass of water} = 1000 \, \text{g}, \quad \text{Molar mass of water} = 18 \, \text{g/mol}. Moles of water=100018=55.56.\text{Moles of water} = \frac{1000}{18} = 55.56.
Step 3: Substitute values into the mole fraction formula
Xurea=4.444.44+55.56.X_{\text{urea}} = \frac{4.44}{4.44 + 55.56}. Xurea=4.4460.00=0.0740.X_{\text{urea}} = \frac{4.44}{60.00} = 0.0740.
Step 4: Express mole fraction as x×103x \times 10^{-3}
Xurea=74×103.X_{\text{urea}} = 74 \times 10^{-3}. x=74.x = 74.
Final Answer: 74

Explanation

Solution

Molality (mm) of urea is given as 4.44 mm, meaning 4.44 moles of urea are dissolved in 1000 g of water.
Step 1: Mole fraction formula
Xurea=Moles of ureaMoles of urea+Moles of waterX_{\text{urea}} = \frac{\text{Moles of urea}}{\text{Moles of urea} + \text{Moles of water}}
Step 2: Calculate moles of water
Mass of water=1000g,Molar mass of water=18g/mol.\text{Mass of water} = 1000 \, \text{g}, \quad \text{Molar mass of water} = 18 \, \text{g/mol}. Moles of water=100018=55.56.\text{Moles of water} = \frac{1000}{18} = 55.56.
Step 3: Substitute values into the mole fraction formula
Xurea=4.444.44+55.56.X_{\text{urea}} = \frac{4.44}{4.44 + 55.56}. Xurea=4.4460.00=0.0740.X_{\text{urea}} = \frac{4.44}{60.00} = 0.0740.
Step 4: Express mole fraction as x×103x \times 10^{-3}
Xurea=74×103.X_{\text{urea}} = 74 \times 10^{-3}. x=74.x = 74.
Final Answer: 74