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Question

Chemistry Question on Colligative Properties

Molal depression constant for a solvent is 4.0kgmol14.0\, kg\, mol^{-1}. The depression in the freezing point of the solvent for 0.03molkg10.03\, mol\, kg^{-1} solution of K2SO4 {K2SO4} is : (Assume complete dissociation of the electrolyte)

A

0.12 K

B

0.36 K

C

0.18 K

D

0.24 K

Answer

0.36 K

Explanation

Solution

KfK_f = 4Kkg/mol4\, K-kg/mol m=0.03mol/kgm = 0.03\, mol/kg i=3i = 3 ΔTf=iKf×m\Delta T_f = iK_f \times m ΔTf=3×4×0.03=0.36K \Delta T_f = 3 \times 4 \times 0.03 = 0.3 6K