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Question

Chemistry Question on p -Block Elements

MnO2+HCl>[Δ]A(g)MnO_2 + HCl { ->[\Delta] } A(g) A(g)+F2(excess)>[573K]B(g) A(g)+ F_{2 {\text{(excess)}}}->[573 \, K] B(g) B(l)+U(s)C(g)+D(g)B(l)+ U(s)\rightarrow C(g)+D(g) The gases A,B,CA, B, C and DD are respectively

A

Cl2,ClF3,UF6,ClFCl_2, ClF_3, UF_6, ClF

B

O2,O2F2,U2O3,OF2O_2, O_2F_2, U_2O_3, OF_2

C

Cl2,ClF,UF6,ClF3Cl_2, ClF, UF_6, ClF_3

D

O2,OF2,U2O3,O2F2O_2, OF_2, U_2O_3, O_2F_2

Answer

Cl2,ClF3,UF6,ClFCl_2, ClF_3, UF_6, ClF

Explanation

Solution

MnO2+4HClCl2(A)+MnCl2+2H2OMnO _{2}+4 HCl \longrightarrow \underset{(A)}{ Cl _{2}}+ MnCl _{2}+2 H _{2} O Cl2+F2in excessCIF3(B)Cl_2 + \underset{\text{in excess}}{F_2} \longrightarrow \underset{(B)}{CIF_3} 3ClF3+UF6(C)+3ClF(D)3ClF_ 3 +\longrightarrow \underset{(C)}{UF_6} + \underset{(D)}{3ClF}