Solveeit Logo

Question

Question: Match the reaction given in column I with the type of reaction mentioned in column II and mark the a...

Match the reaction given in column I with the type of reaction mentioned in column II and mark the appropriate choice.

Column IColumn II
(A)(i)

β

elimination

(B)$$CH_{3}CH_{2}Br\overset{\quad AgOH\quad}{\rightarrow}CH_{3}CH_{2}OH$$(ii)

SN1

nucleophilic

substitution

(C)$${CH_{3}CH = CH_{2} + HBr\overset{\quad peroxide\quad}{\rightarrow} }{CH_{3}CH_{2}CH_{2}Br}$$(iii)

SN2

nucleophilic

substitution

(D)CH3 − CH2Br + alc.KOHCH2 = CH2(iv)

Kharasch

effect

A

(A)(iv),(B)(i),(C)(ii),(D)(iii)(A) \rightarrow (iv),(B) \rightarrow (i),(C) \rightarrow (ii),(D) \rightarrow (iii)

B

(A)(ii),(B)(iii),(C)(iv),(D)(i).(A) \rightarrow (ii),(B) \rightarrow (iii),(C) \rightarrow (iv),(D) \rightarrow (i).

C

(A)(i),(B)(ii),(C)(iv),(D)(iii)(A) \rightarrow (i),(B) \rightarrow (ii),(C) \rightarrow (iv),(D) \rightarrow (iii)

D

(A)(iii),(B)(i),(C)(ii),(D)(iv)(A) \rightarrow (iii),(B) \rightarrow (i),(C) \rightarrow (ii),(D) \rightarrow (iv)

Answer

(A)(i),(B)(ii),(C)(iv),(D)(iii)(A) \rightarrow (i),(B) \rightarrow (ii),(C) \rightarrow (iv),(D) \rightarrow (iii)

Explanation

Solution

In (i) is major product while is minor product according to saytzeff’s rule.