Question
Question: Match the reaction given in column I with the type of reaction mentioned in column II and mark the a...
Match the reaction given in column I with the type of reaction mentioned in column II and mark the appropriate choice.
Column I | Column II | ||
---|---|---|---|
(A) | ![]() | (i) | β− elimination |
(B) | $$CH_{3}CH_{2}Br\overset{\quad AgOH\quad}{\rightarrow}CH_{3}CH_{2}OH$$ | (ii) | SN1 nucleophilic substitution |
(C) | $${CH_{3}CH = CH_{2} + HBr\overset{\quad peroxide\quad}{\rightarrow} }{CH_{3}CH_{2}CH_{2}Br}$$ | (iii) | SN2 nucleophilic substitution |
(D) | CH3 − CH2Br + alc.KOH→CH2 = CH2 | (iv) | Kharasch effect |
A
(A)→(iv),(B)→(i),(C)→(ii),(D)→(iii)
B
(A)→(ii),(B)→(iii),(C)→(iv),(D)→(i).
C
(A)→(i),(B)→(ii),(C)→(iv),(D)→(iii)
D
(A)→(iii),(B)→(i),(C)→(ii),(D)→(iv)
Answer
(A)→(i),(B)→(ii),(C)→(iv),(D)→(iii)
Explanation
Solution
In (i) is major product while
is minor product according to saytzeff’s rule.