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Question

Chemistry Question on coordination compounds

Match List-I with List-II.
Reaction & Reagent
Choose the correct answer from the options given below:

A

(A)-(IV), (B)-(I), (C)-(III), (D)-(II)

B

(A)-(II), (B)-(III), (C)-(I), (D)-(IV)

C

(A)-(II), (B)-(I), (C)-(III), (D)-(IV)

D

(A)-(IV), (B)-(III), (C)-(I), (D)-(II)

Answer

(A)-(IV), (B)-(III), (C)-(I), (D)-(II)

Explanation

Solution

(A) Oxidation of phenol to benzoquinone: This reaction uses Na2Cr2O7\text{Na}_2\text{Cr}_2\text{O}_7 and H2SO4\text{H}_2\text{SO}_4 as the oxidizing agents.

(B) Kolbe’s reaction: It involves carboxylation of phenol using NaOH\text{NaOH} and CO2\text{CO}_2, followed by acidification with HCl\text{HCl}.

(C) Reimer-Tiemann reaction: This reaction introduces an aldehyde group on the phenol ring using NaOH\text{NaOH} and CHCl3\text{CHCl}_3.

(D) Williamson’s synthesis: It prepares ethers by reacting phenoxide with CH3Cl\text{CH}_3\text{Cl} in the presence of NaOH\text{NaOH}.

The Correct answer is: (A)-(IV), (B)-(III), (C)-(I), (D)-(II)