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Question

Chemistry Question on Chemical bonding and molecular structure

Match List-I with List-II.List-I
(Molecule)| List-II
(Shape)
---|---
(A) NH3NH_3| (I) Square pyramid
(B) BrF5BrF_5| (II) Tetrahedral
(C) PCL5PCL_5| (III) Trigonal pyramidal
(D) CH4CH_4| (IV) Trigonal bipyramidal
Choose the correct answer from the options given below:

A

A-IV, B-III, C-I, D-II

B

A-II, B-IV, C-I, D-III

C

A-III, B-I, C-IV, D-II

D

A-III, B-IV, C-I, D-II

Answer

A-III, B-I, C-IV, D-II

Explanation

Solution

NH3_3: Trigonalpyramidal ({sp}3^3 hybridization with one lone pair on N).
BrF5_5: Squarepyramidal ({sp}3^3{d}2^2 hybridization with one lone pair on Br).
PCl5_5:Trigonalbipyramidal ({sp}3^3{d} hybridization, no lone pairs).
CH4_4: Tetrahedral ({sp}3^3 hybridization, no lone pairs).
Matching: A-III, B-I, C-IV, D-II.
Final Answer: A-III, B-I, C-IV, D-II.