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Question

Chemistry Question on Rate of a Chemical Reaction

Match List I with List II.

List-IList-II
A. Benzene sulphonyl chlorideI. Test for primary amines
B. Hoffmann bromamide reactionII. Anti Saytzeff
C. Carbylamine reactionIII. Hinsberg reagent
D. Hoffmann orientationIV. Known reaction of Isocyamates

Choose the correct answer from the options given below:

A

A-IV, B-III, C-II, D-I

B

A-IV, B-II, C-I, D-II

C

A-III, B-IV, C-I, D-II

D

A-IV, B-III, C-I, D-II

Answer

A-III, B-IV, C-I, D-II

Explanation

Solution

(A) Benzene sulphonyl chloride is also known as Hinsberg reagent.
(B) Hoffmann bromamide reaction involves conversion of amide to amine having one C-atom less. This reaction involves isocyanate as intermediate.
(C) Carbylamine reaction is a test given by all primary amines.
(D) Hoffmann orientation refers to the addition of molecules to unsymmetrical alkenes according to anti Saytzeff's rule.
• Correct match is: A - III; B - IV; C - I; D - II