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Question

Chemistry Question on subshell electronic configuration

Match List-I with List-II:List-I ( Ions )List-II ( No. of unpaired electrons )
AZn2+^{2+}
BCu2+^{2+}
CNi2+^{2+}
DFe2+^{2+}
Choose the correct answer from the options given below:
A

(A)-(I), (B)-(II), (C)-(III), (D)-(IV)

B

(A)-(I), (B)-(III), (C)-(II), (D)-(IV)

C

(A)-(I), (B)-(III), (C)-(IV), (D)-(II)

D

(A)-(III), (B)-(IV), (C)-(I), (D)-(II)

Answer

(A)-(I), (B)-(III), (C)-(IV), (D)-(II)

Explanation

Solution

1. Zn2+^{2+}: Electron configuration of Zn is [Ar] 3d10^{10}. The ion has 0 unpaired electrons. Therefore, (A) - (I).\\\2. Cu2+^{2+}: Electron configuration of Cu is [Ar] 3d10^{10} 4s1^1. The ion has 1 unpaired electron after losing 2 electrons. Therefore, (B) - (III).\\\3. Ni2+^{2+}: Electron configuration of Ni is [Ar] 3d8^8 4s2^2. The ion has 2 unpaired electrons. Therefore, (C) - (IV).\\\4. Fe2+^{2+}: Electron configuration of Fe is [Ar] 3d6^6 4s2^2. The ion has 4 unpaired electrons. Therefore, (D) - (II).\\\Thus, the correct matches are: (A) - (I), (B) - (III), (C) - (IV), (D) - (II).