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Chemistry Question on Organic Chemistry- Some Basic Principles and Techniques

Match List I with List II
List-I
(Conversion)| **List-II **
(Shape/geometry)
---|---
(A)| 1 mol of H2O to O2| (I)| 3F
(B)| 1 mol of MnO-4 to Mn2+| (II)| 2F
(C)| 1.5 mol of Ca from molten CaCl2| (III)| 1F
(D)| 1 mol of FeO to Fe2O3| (IV)| 5F

Choose the correct answer from the options given below:

A

A-II, B-IV, C-I, D-III

B

A-III, B-IV, C-I, D-II

C

A-II, B-III, C-I, D-IV

D

A-III, B-IV, C-II, D-I

Answer

A-II, B-IV, C-I, D-III

Explanation

Solution

1. For H2OO2H_2O \to O_2, 4 electrons are needed per oxygen atom. Hence, 2 moles of H2OH_2O require 4F for 1 mole of O2O_2.
2. For MnO4Mn2+MnO_4^- \to Mn^{2+}, 5 electrons per mole are required, so 5F.
3. For CaCl2CaCl_2, 2 electrons are required per Ca, so 1.5 moles require 3F.
4. For FeOFe2O3FeO \to Fe_2O_3, 2 moles of FeO require 2F.