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Question

Question: Mark the correct order of decreasing acid strength of the following compouns. <img src="https://cdn...

Mark the correct order of decreasing acid strength of the following compouns.

A

(v) > (iv) > (ii) > (i) > (iii)

B

(ii) > (iv) > (i) > (iii) > (v)

C

(iv) > (v) > (iii) > (ii) > (i)

D

(v) > (iv) > (iii) > (ii) > (i)

Answer

(ii) > (iv) > (i) > (iii) > (v)

Explanation

Solution

The electron withdrawing group (NO2)( - NO_{2}) increases the acidity of phenols and the electron donating group (OCH3)( - OCH_{3}) decreases the acidity of phenols. The effect at p-position is greater than at m-position.