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Question

Chemistry Question on Chemical bonding and molecular structure

Lattice energy of alkali metal chlorides follows the order :

A

LiCl>NaCl>KCl>RbCl>CsClLiCl>NaCl>KCl>RbCl>CsCl

B

CsCl>NaCl>KCl>RbCl>LiClCsCl>NaCl>KCl>RbCl>LiCl

C

LiCl>CsCl>NaCl>KCl>RbClLiCl>CsCl>NaCl>KCl>RbCl

D

NaCl>LiCl>KCl>RbCl>CsClNaCl>LiCl>KCl>RbCl>CsCl

Answer

LiCl>NaCl>KCl>RbCl>CsClLiCl>NaCl>KCl>RbCl>CsCl

Explanation

Solution

Lattice energy depends on the size of ion and it decreases with increase in size.
\because The size of alkali metals increases from LiLi to CsCs.
\therefore Lattice energy of alkali metal halides is as follows:
LiCl>NaCl>KCl>RbCl>CsClLiCl > NaCl > KCl > RbCl > CsCl