Solveeit Logo

Question

Question: Lanthanum is grouped with f-block elements because (A) it has partially filled f-block orbitals ...

Lanthanum is grouped with f-block elements because
(A) it has partially filled f-block orbitals
(B) it is just before Ce in the periodic table
(C) it has both partially filled f and d-orbitals
(D) the properties of lanthanum are very similar to the elements of 4f4f block

Explanation

Solution

Lanthanides are f-block elements. Their atomic number ranges from 5757 to 7171 . They are also called rare earth metals. They have similar configurations and similar physical and chemical behavior. They are relatively soft metals. Silvery-white metals that tarnish when exposed to air, forming their oxides.

Complete answer:
The lanthanide family contains fifteen metallic elements (from lanthanum to lutetium). The valence electrons of the lanthanide family are present in the 4f orbital. All of them are known to form Ln3+ cations. Lanthanides show variable oxidation states. They also show +2, +3, and +4 oxidation states. Among them, the most stable oxidation state of Lanthanides is +3.
The general electronic configuration of lanthanides is [Xe] 4f114 5d 016s2\left[ {Xe} \right]{\text{ }}4{f^{1 - 14}}{\text{ }}5d{{\text{ }}^{0 - 1}}6{s^2} .
In lanthanide the electron enters in 6s orbital therefore lanthanides are placed in period number 6 and group number 33 .
The energies of 4f4f and 5d5d electrons are almost close to each other and so 5d5d orbital remains vacant and the electrons enter into the 4f4f orbital. Also, they have partially filled f-orbitals. F-orbitals of electron shells are filled with n  2n{\text{ }}-{\text{ }}2 electrons. This is the reason why lanthanum is grouped with f-block elements.
Therefore the correct option is A. it has partially filled f-block orbitals.

Note:
Lanthanide name is given after their first element of the series lanthanum. They all show similar properties. With the increase in the atomic number there is a decrease in the size of the atoms this is called lanthanide contraction. It is only shown by lanthanides.