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Question

Chemistry Question on Isomerism in Coordination Compounds

L-isomer of a compound ‘A’ (C4H8O4)(C_4H_8O_4) gives a positive test with [Ag(NH3)2]+[Ag(NH_3)^2]^+. Treatment of ‘A’ with acetic anhydride yields triacetate derivative. Compound ‘A’ produces an optically active compound (B) and an optically inactive compound (C) on treatment with bromine water and HNO3HNO_3 respectively. Compound (A) is:

A

Option a

B

Option b

C

Option c

D

Option d

Answer

Option a

Explanation

Solution

When(A) is given heat with acetic anhydride, acetylation occurs and OH–OH group is replaced by and hence, triacetate is formed.

Hence, the correct option is (A).