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Question

Chemistry Question on d -and f -Block Elements

KMnO4KMnO _4 oxidises II ^{-}in acidic and neutral/faintly alkaline solution, respectively, to

A

IO3&IO3IO _3^{-} \& IO _3^{-}

B

I2&IO3I _2 \& IO _3^{-}

C

I2&I2I _2 \& I _2

D

IO3&I2IO _3^{-} \& I _2

Answer

I2&IO3I _2 \& IO _3^{-}

Explanation

Solution

The correct answer is (B) : I2&IO3I _2 \& IO _3^{-}
In acidic medium
2MnO4−​+10I−+16H+→2Mn2++5I2​+8H2​O
In neutral/faintly alkaline solution
2MnO4−​+I−+H2​O→2MnO2​+2OH−+IO3−​