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Chemistry Question on Acids and Bases

KuK _{ u } values for acids H2SO3,HNO2,CH3COOHH _{2} SO _{3}, HNO _{2}, CH _{3} COOH and HCNHCN are respectively 1.3×102,4×104,1.8×1051.3 \times 10^{-2}, 4 \times 10^{-4}, 1.8 \times 10^{-5} and 4×10104 \times 10^{-10}, which of the above acids produces stronger conjugate base in aqueous solution?

A

H2SO3H_2SO_3

B

HNO2HNO_2

C

CH3COOHCH_3COOH

D

HCNHCN

Answer

HCNHCN

Explanation

Solution

Ka(HCN)=4×1010K _{ a }( HCN )=4 \times 10^{-10}
HCNH++CNHCN \rightleftharpoons H ^{+}+ CN ^{-}
Weaker the acid, stronger the conjugate base.