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Question: It requires 40 ml of 0.5 (M) Ce<sup>4+</sup> to titrate 10 ml of 1 (M) Sn<sup>2+</sup> where by Sn<s...

It requires 40 ml of 0.5 (M) Ce4+ to titrate 10 ml of 1 (M) Sn2+ where by Sn2+ is oxidised to Sn4+. What is the oxidation state of cerium in the reduction product ?

A
  • 3
B
  • 2
C
  • 1
D

Zero

Answer
  • 3
Explanation

Solution

Moles of Ce4+ reacted = 20 × 10–3 moles

2 moles of Ce4+ reacts with ( 4– x) moles of Sn2+

\ 20 × 10–3 moles of Ce4+ reacts with

( 4– x) × 10–2 moles of Sn2+

\ (4 – x) × 10–2 = 10 × 10–3

\ 4 – x = 1

or x = + 3.