Question
Question: It requires 40 ml of 0.5 (M) Ce<sup>4+</sup> to titrate 10 ml of 1 (M) Sn<sup>2+</sup> where by Sn<s...
It requires 40 ml of 0.5 (M) Ce4+ to titrate 10 ml of 1 (M) Sn2+ where by Sn2+ is oxidised to Sn4+. What is the oxidation state of cerium in the reduction product ?
A
- 3
B
- 2
C
- 1
D
Zero
Answer
- 3
Explanation
Solution
Moles of Ce4+ reacted = 20 × 10–3 moles
2 moles of Ce4+ reacts with ( 4– x) moles of Sn2+
\ 20 × 10–3 moles of Ce4+ reacts with
( 4– x) × 10–2 moles of Sn2+
\ (4 – x) × 10–2 = 10 × 10–3
\ 4 – x = 1
or x = + 3.