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Question: Is cyclopropenyl cation, \( {C_3}{H_3}^ + \) aromatic?...

Is cyclopropenyl cation, C3H3+{C_3}{H_3}^ + aromatic?

Explanation

Solution

Cyclopropenyl cation is a cyclopropane with a positive charge on one carbon atom formed by the loss of one hydrogen atom. The compounds that are cyclic, planar, conjugation of pi-electrons and obeying Huckel’s rule can be defined as aromatic compounds, these are stable compounds.

Complete answer:
Cycloalkenes are alkenes arranged in a cyclic manner. Alkenes are unsaturated hydrocarbons consisting of double bonded carbon atoms. When one hydrogen atom is removed from the cyclopropene, it forms a compound known as cyclopropenyl cation which is represented by a formula of C3H3+{C_3}{H_3}^ + .
Aromatic compounds are the compounds that are cyclic, planar which means all the carbon atoms have sp2s{p^2} hybridization, conjugation of π\pi electrons, and obeying Huckel’s rule. Huckel's rule states that the compound must contain (4n+2)π\left( {4n + 2} \right)\pi electrons, where n is a positive whole number.
The structure of cyclopropenyl cation (C3H3+)\left( {{C_3}{H_3}^ + } \right) is

The above molecule is in cyclic arrangement, all the carbon atoms are sp2s{p^2} hybridized, as the double bonded are sp2s{p^2} hybridized and the carbocation is also sp2s{p^2} hybridized, the double bond and the positive charge are in conjugation, and the compound has two pi-electrons which obeys Huckel’s rule as (4(0)+2)π=2π\left( {4\left( 0 \right) + 2} \right)\pi = 2\pi electrons. cyclopropenyl cation obeys all the conditions required to be an aromatic compound.
Thus, cyclopropenyl cation, C3H3+{C_3}{H_3}^ + is an aromatic compound.

Note:
Conjugation means the two double bonds or one double bond and charge separated by a single bond. In the above molecule, charge and double bond are separated by a single bond. Carbocation is the carbon bearing a positive charge and involves in sp2s{p^2} hybridization.