Question
Question: Is \( Br \) or \( Cl \) more stable?...
Is Br or Cl more stable?
Solution
Br and Cl both belong to the same group which is group 17 . As we move down the group or across the period there are certain trends followed by the elements. For these the stability of an atom one must be familiar with the reactivity of the elements.
Complete answer:
The group 17 is called the halogens. Since it lacks only one electron to attain the noble gas electronic configuration, it readily adds one electron to attain the noble gas configuration.
To find which of the given element is more stable let us first find what are the factors that affect the ease of electron acceptance:
Number of protons- Since the number of protons in Br is 35 and in Cl is 17 , therefore Br nucleus has stronger attraction for an electrons than the Cl
Atomic radius- Since Br has one more electron shell than Cl atom the distance between the nucleus and the outermost shell of Br is larger and therefore has to attract an electron further away, and greater distance means the electron is attracted less strongly.
Shielding – Again due to one more shell of Br than the Cl , it has more shielding Cl meaning attraction between nucleus and electron is weaker.
Due to all these factors the electron is more attracted into the Cl atom than that of Br , Cl is more reactive than Br . For an element to be more stable it should be less reactive. Since Br is less reactive, therefore will be more stable.
Note:
As we move down the group the reactivity decreases. Therefore F is most reactive and At the least reactive. This group has highly negative electron gain enthalpy and metallic characters increases as we go down the group.