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Question

Question: Is \( Br \) or \( Cl \) more stable?...

Is BrBr or ClCl more stable?

Explanation

Solution

BrBr and ClCl both belong to the same group which is group 1717 . As we move down the group or across the period there are certain trends followed by the elements. For these the stability of an atom one must be familiar with the reactivity of the elements.

Complete answer:
The group 1717 is called the halogens. Since it lacks only one electron to attain the noble gas electronic configuration, it readily adds one electron to attain the noble gas configuration.
To find which of the given element is more stable let us first find what are the factors that affect the ease of electron acceptance:
Number of protons- Since the number of protons in BrBr is 3535 and in ClCl is 1717 , therefore BrBr nucleus has stronger attraction for an electrons than the ClCl
Atomic radius- Since BrBr has one more electron shell than ClCl atom the distance between the nucleus and the outermost shell of BrBr is larger and therefore has to attract an electron further away, and greater distance means the electron is attracted less strongly.
Shielding – Again due to one more shell of BrBr than the ClCl , it has more shielding ClCl meaning attraction between nucleus and electron is weaker.
Due to all these factors the electron is more attracted into the ClCl atom than that of BrBr , ClCl is more reactive than BrBr . For an element to be more stable it should be less reactive. Since BrBr is less reactive, therefore will be more stable.

Note:
As we move down the group the reactivity decreases. Therefore FF is most reactive and AtAt the least reactive. This group has highly negative electron gain enthalpy and metallic characters increases as we go down the group.