Solveeit Logo

Question

Chemistry Question on States of matter

Internal energy and pressure of a gas per unit volume are related as

A

p=23Ep=\frac{2}{3}E

B

p=32Ep=\frac{3}{2}E

C

p=12Ep=\frac{1}{2}E

D

p = 2E

Answer

p=23Ep=\frac{2}{3}E

Explanation

Solution

The average translational kinetic energy of a gas
molecule is 12\frac{1}{2} mu2...(i)m \overline{u}^2\, \, \, \, \, \, \, \, \, ...(i)
The total energy of the whole of the gas containing
N molecules is
Ek=12mNu2...(i)E_k=\frac{1}{2}m N \overline{u}^2\, \, \, \, \, \, \, \, \, ...(i)
The kinetic gas equation is
pV=13mNu2...(ii)pV=\frac{1}{3}m N \overline{u}^2\, \, \, \, \, \, \, \, \, ...(ii)
pV=23×12mNu2pV=\frac{2}{3}\times\frac{1}{2}m N \overline{u}^2
pV=23Ek...(iii)pV=\frac{2}{3} E_k\, \, \, \, \, \, \, \, \, \, \, \, \, \, ...(iii)
so, p=23Ek\, \, \, \, \, \, \, \, \, \, \, \, p=\frac{2}{3} E_kper unit volume