Question

Initial concentration of reactant for ${n^{th}}$order reaction is '$a$'. Which of the following relations is correct about ${t_{1/2}}$​ of the reaction?
(A)$\;ln\;{t_{1/2}} = ln\left( {constant} \right) - \left( {n - 1} \right)lo{g_{e}}a$
(B)$\;ln\;{t_{1/2}} = ln\;n + ln\left( {constant} \right) - ln\;a$
(C)${t_{1/2}}ln\;n = ln\left( {constant} \right) + ln\;{a_0}$ ​
(D)$ln\;\;{t_{1/2}} = n\;\;ln\;\;{a_0}$

Answer 1

The convergences of reactants and the pace of a reaction with these fixations, we will view from the outset and second request reactions just as half-life. For a Pseudo-${n^{th}}$-Order Reaction, the reaction rate consistent $k$ is supplanted by the apparent reaction rate steady $k'$.

Complete step by step answer:
If the reaction isn't worked out explicitly to show an estimation of ${\nu _A}$, the worth is thought to be $1$ and doesn't appear in these conditions.
One approach to determine the request $n$ and to get an estimated incentive for $k$ or $k'$, is with the strategy for half-lives. The half-life ${t_{1/2}}$is characterized as the time needed for the initial fixation to be divided: ${\left[ A \right]_{{t_{1/2}}}}{\text{ }} = {\text{ }}{\left[ A \right]_t} = 0/2$
This shows that there is an overall relationship for all estimations of $n$ (counting $n{\text{ }} = {\text{ }}1$) between the initial focus and the half-life for a reaction concentrated with various initial fixations at a similar temperature: $\dfrac{{{t_{1/2}}}}{{{{\left[ A \right]}_t}}} = {0^{n{\text{ }} - {\text{ }}1}}{\text{ }} = {\text{ }}constant$.
On the off chance that the reaction is First-Order, the half-life won't change with fixation.
On the off chance that the request is more noteworthy than one, the half-life will diminish as the initial focus is expanded.
In the event that the request is short of what one, the half-life will increment as the initial fixation is expanded.
The request for the reaction ($n$) might be found by assurance of the half-lives for a reaction learned at two initial focuses. On the off chance that the subsequent focus is equivalent to multiple times the first: $\dfrac{{{{\left( {{t_{1/2}}} \right)}_1}}}{{{{\left( {{t_{1/2}}} \right)}_2}}} = {\text{ }}{10^{n{\text{ }} - {\text{ }}1}}$.
Whenever n has been determined, $k$ or $k'$ can be determined from the relationship above,
$\dfrac{{\left( {{2^{n{\text{ }} - {\text{ }}1}}{\text{ }} - {\text{ }}1} \right)}}{{{{\left[ A \right]}_t}}} = {0^{n{\text{ }} - {\text{ }}1}}{\text{ }} = {\text{ }}{\nu _A}^{\left( {n{\text{ }} - {\text{ }}1} \right)}{\text{ }}k{t_{1/2}}$.
So, the required answer is as follows…
${t_{1/2}} \propto \dfrac{{1}}{{{a^{n - 1}}}}$
${t_{1/2}} = k\dfrac{{1}}{{{a^{n - 1}}}}$
$ln\;\;{t_{1/2}} = ln\;\;k - (n - 1)lo{g_e}a$
Hence, the correct option is (A).

Note:
The best estimations of the reaction rate consistent ($k$) can be acquired with information taken in the centre third of the reaction (from${\left[ A \right]_t}{\text{ }} = {\text{ }}\left( {\dfrac{2}{3}} \right){\text{ }}{\left[ A \right]_t} = 0{\text{ }}to{\text{ }}{\left[ A \right]_t}{\text{ }} = {\text{ }}\left( {\dfrac{1}{3}} \right){\text{ }}{\left[ A \right]_t} = 0$). Straight Least Squares relapse with $Y{\text{ }} = {\text{ }}1/{\left[ A \right]_t}^{n{\text{ }} - {\text{ }}1}$and $X{\text{ }} = {\text{ }}t$ gives ${\nu _A}^{\left( {n{\text{ }} - {\text{ }}1} \right)k}$ or ${\nu _A}^{\left( {n{\text{ }} - {\text{ }}1} \right)k'}$as the slant.