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Question

Chemistry Question on Alcohols, Phenols and Ethers

In Williamson's synthesis, ethoxyethane is prepared by

A

passing ethanol over heated alumina

B

heating sodium ethoxide with ethyl bromide

C

treating ethyl alcohol with excess of H'. H2SO4H_2SO_4 at 430 -- 440 K

D

heating ethanol with dry Ag2OAg_2O

Answer

heating sodium ethoxide with ethyl bromide

Explanation

Solution

sodiumethoxideCH3CH2ONa+bromoethaneC2H5BrsynthesisWilliamsonsethoxyethaneCH3CH2OCH2CH3+NaBr^{ CH_3CH_2ONa }_{ sodium ethoxide } \, + \, ^{C_2 H_5 Br}_{ bromo \, ethane} \, \xrightarrow[synthesis] {Williamson's } \, ^{ CH_3 CH_2 OCH_2 CH_3}_{ ethoxyethane } + NaBr