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Question

Chemistry Question on Haloalkanes and Haloarenes

In which of the reactions given below does H2PO4- behave as an acid?(i) H3PO4+H2O→H3O++H2PO4−(ii) H2PO4−+H2O→H3O++HPO42−(iii) H2PO4−+OH−→H3PO4+O2−

A

(A) (i) and (ii)

B

(B) Only (ii)

C

(C) Only (i)

D

(D) Only (iii)

Answer

(B) Only (ii)

Explanation

Solution

Explanation:
Only in the reaction (ii), H2PO4- behaves as a proton donor and is an acid by both Arrhenius and Bronsted concepts.