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Question: In which of the following reactions \(H_{2}O\)acts as a Bronsted acid?...

In which of the following reactions H2OH_{2}Oacts as a Bronsted acid?

A

H2O(l)+NH3(aq)H_{2}O_{(l)} + NH_{3(aq)} OH(aq)+NH4(aq)+O{H^{-}}_{(aq)} + NH_{4(aq)}^{+}

B

H2O(l)+H2S(aq)H_{2}O_{(l)} + H_{2}S_{(aq)} H3O+(aq)+HS(aq)H_{3}{O^{+}}_{(aq)} + H{S^{-}}_{(aq)}

C

H2O(i)+H2O(I)H_{2}O_{(i)} + H_{2}O_{(I)} H3O+(aq)+OH(aq)H_{3}{O^{+}}_{(aq)} + O{H^{-}}_{(aq)}

D

H+(aq)+OH(aq){H^{+}}_{(aq)} + O{H^{-}}_{(aq)} H2O(I)H_{2}O_{(I)}

Answer

H2O(l)+NH3(aq)H_{2}O_{(l)} + NH_{3(aq)} OH(aq)+NH4(aq)+O{H^{-}}_{(aq)} + NH_{4(aq)}^{+}

Explanation

Solution

: H2OH_{2}Oacts as a Bronsted acid and gives proton to react with a base.

H2OAcid+NH3base\underset{Acid}{H_{2}O} + \underset{base}{NH_{3}} OH+NH4+OH^{-} + NH_{4}^{+}

In H2Obase+H2SacidH3O++HS\underset{base}{H_{2}O} + \underset{acid}{H_{2}S} \rightarrow H_{3}O^{+} + HS^{-}

H2OH_{2}Oacts as a base with H2SH_{2}S