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Question

Chemistry Question on Entropy and free energy

In which of the following processes entropy increases?
A. A liquid evaporates to vapour.
B. Temperature of a crystalline solid lowered from 130 K to 0 K.
C. 2NaHCO3(s) -> Na2CO3(s)+CO2(g)+H2O(g)
D. Cl2(g) -> 2Cl(g)
Choose the correct answer from the options given below:

A

A and C

B

A, B and D

C

A, C and D

D

C and D

Answer

A, C and D

Explanation

Solution

- A: A liquid evaporating to vapor increases entropy because gas has higher randomness.
- C: Decomposition of NaHCO3NaHCO_3 increases entropy as solid converts to gases (CO2,H2OCO_2, H_2O).
- D: Dissociation of Cl2Cl_2 into 2Cl2Cl increases entropy due to an increase in the number of particles.
- B: Lowering temperature decreases entropy as randomness decreases.