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Question: In which of the following compounds the carbon marked with asterisk is expected to have greatest pos...

In which of the following compounds the carbon marked with asterisk is expected to have greatest positive charge?

A

CH3CH2Cl\overset{*}{C}H_{3} - CH_{2} - Cl

B

CH3CH2Mg+Cl\overset{*}{C}H_{3} - CH_{2} - Mg^{+}Cl^{-}

C

CH3CH2Br\overset{*}{C}H_{3} - CH_{2} - Br

D

CH3CH2CH3\overset{*}{C}H_{3} - CH_{2} - CH_{3}

Answer

CH3CH2Cl\overset{*}{C}H_{3} - CH_{2} - Cl

Explanation

Solution

: As Cl is most electronegative element among Cl, Mg, Br and C thus, it has grater – I effect and the asterisk marked carbon in CH3CH2ClCH_{3} - CH_{2} - Cl is expected to have greater positive charge.