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Question

Chemistry Question on Aldehydes, Ketones and Carboxylic Acids

In this reaction, CH3CHO+HCNCH3CH(OH)CNCH _{3} CHO + HCN \rightarrow CH _{3} CH ( OH ) CN  H.OH CH3CH(OH)COOH\stackrel{\text { H.OH }}{\longrightarrow} CH _{3} CH ( OH ) COOH an asymmetric centre is generated. The acid obtained would be

A

50% D + 50% L-isomer

B

20% D + 80% L-isomer

C

D-isomer

D

L-isomer

Answer

50% D + 50% L-isomer

Explanation

Solution

The correct answer is A:50%D+50%L-isomer
Lactic acid obtained in the given reaction is an optically active compound due to the presence of chiral C-atom. It exists as d and l-forms whose ratio is 1 : 1.