Solveeit Logo

Question

Question: In the two vessels of same volume, atomic hydrogen and helium at pressure 1 atm and 2 atm are filled...

In the two vessels of same volume, atomic hydrogen and helium at pressure 1 atm and 2 atm are filled. If temperature of both the samples is same, then average speed of hydrogen atoms <CH>< C_{H} > will be related to that of helium <CHe>< C_{He} > as

A

<CH>=2<CHe>< C_{H} > = \sqrt{2} < C_{He} >

B

<CH>=<CHe>< C_{H} > = < C_{He} >

C

<CH>=2<CHe>< C_{H} > = 2 < C_{He} >

D

<CH>=<CHe>2< C_{H} > = \frac{< C_{He} >}{2}

Answer

<CH>=2<CHe>< C_{H} > = 2 < C_{He} >

Explanation

Solution

Average velocity of gas molecule is

vav=8RTπMv_{av} = \sqrt{\frac{8RT}{\pi M}}Žvav1Mv_{av} \propto \frac{1}{\sqrt{M}}

Ž<CH><CHe>=MHeMH=41=2\frac{< C_{H} >}{< C_{He} >} = \sqrt{\frac{M_{He}}{M_{H}}} = \sqrt{\frac{4}{1}} = 2 Ž <CH>=2<CHe>< C_{H} > = 2 < C_{He} >